PFAS Free Filament: Avoid Forever Chemicals in 3D Printing

Discover PFAS free filament options and avoid forever chemicals and microplastics in 3D printing.

Written on 11 July 2025

The Real Deal on PFAS in 3D Printing Filaments: What Every Health-Conscious Mom Should Know

As a mom who’s always on a mission to keep my family safe and healthy—and with a science background that loves to dig into the “why” behind things—I’ve been wondering: are 3D printing filaments actually free from PFAS (those pesky forever chemicals)? If you’re like me, looking for products that won’t bring unwanted toxins into your home, let’s break down the facts about PFAS free filament and how to spot filament without microplastics.

Here’s the quick scoop: most standard 3D printing filaments like PLA, ABS, and PETG don’t contain PFAS. But—and there’s always a but—PFAS can sneak in through post-processing chemicals, manufacturing practices, composite filaments, or even packaging. Let’s explore the science—and the savvy shopping tips—that will help you print safe and sound.


What’s Inside Your Filament? Understanding PFAS Risks in Common Materials

Standard Thermoplastics: Your Everyday Safe Bets

Popular filaments like PLA (polylactic acid) and ABS (acrylonitrile butadiene styrene) are made without PFAS. According to EPA research on 3D printing emissions, these plastics release some volatile organic compounds (VOCs) and ultrafine particles when melted, but not PFAS. Same goes for PETG (polyethylene terephthalate glycol)—its chemical resistance comes from ester bonds, not fluorinated compounds, so it stays PFAS free by design (learn more about PETG).

Eco-Friendly, Bio-Based Filaments Without Microplastics

If you want to dodge microplastics and ditch forever chemicals altogether, bio-based filaments like PHA (polyhydroxyalkanoate) are fantastic choices. Made by bacterial fermentation, brands like ColorFabb’s allPHA and Beyond Plastic’s FLEX PHA offer biodegradable filaments that naturally break down in soil within a few months—no lasting nasties here! Independent tests confirm these are free of PFAS and microplastics (ColorFabb sustainability, Beyond Plastic FLEX PHA).

Composite and Engineering Filaments: A Bit More Complex

Some specialty filaments require a closer look:

  • Tullomer™ by Z-Polymers is a shining star—a high-strength composite filament that rivals aluminum without using any fluorinated additives. That means no forever chemicals here, just strong, safe prints (Tullomer™ introduction).

  • Ceramic-infused monoliths designed for water filtration can actually remove PFAS from water. They use materials like indium oxide that adsorb these contaminants—but the filament itself doesn’t contain PFAS (Bath University PFAS removal).

  • A heads up: fluorinated coatings on HDPE containers used to store raw materials may cause PFAS contamination through leaching (PFAS in plastic packaging). So it pays to know where your filament pellets are coming from.


How Forever Chemicals Might Creep Into Your 3D Printing Process

Post-Processing Pitfalls: Watch Those Chemicals!

One sneaky way PFAS can show up is during finishing. Vapor smoothing—great for getting rid of layer lines—used to rely on solvents like heptafluoroisopropanol (HFIP), which is loaded with PFAS. The good news? Companies like Dyemansion now offer PFAS free filament finishing with their VaporFuse system that uses green solvents instead (Dyemansion PFAS-free solution). Win for moms who want flawless prints without toxic trade-offs!

Emissions During Printing: Tiny Particles, Big Concerns

While your printer doesn’t spew PFAS directly, high heat extrusion creates ultrafine particles (<100 nm) that can pick up airborne pollutants—including PFAS if they’re around. The University of Bath’s research shows nanoparticles act like tiny pollutant taxis—but the filaments themselves don’t generate PFAS through heating (Bath University nanoparticle study). EPA studies back this up: emissions come from polymer breakdown, not fluorinated chemicals (EPA emissions study).

Supply Chain Surprises: Packaging Matters

Some raw filament pellets come in HDPE containers treated with fluorine gas to toughen them up. Unfortunately, this process can create PFAS contaminants like PFOA that might leach into your filament (PFAS in HDPE containers). So be sure your supplier prioritizes pfas free filament sourcing!


PFAS-Free Filament and Industry Innovations You Can Get Excited About

Sustainable Filaments That Check All the Boxes

  • PHA-based filaments biodegrade fully in home compost within six months and perform mechanically close to ABS (ColorFabb sustainability).

  • Tullomer™ offers a PFAS-free, super-strong filament option priced at $45–$65/kg, already trusted by aerospace pros (Tullomer™ introduction).

  • Water-soluble supports like polyvinyl alcohol (PVA) help avoid the need for PFAS-containing release agents in multi-material prints.

Processing Aids Without the Forever Chemicals

The industry is shifting away from fluorinated polymer processing aids (PPAs). Innovations like SILIKE’s SILIMER and Ampacet’s masterbatches provide effective PFAS-free alternatives that reduce die buildup 40–60%, comply with FDA food-contact standards, and speed up production over traditional options (SILIKE PFAS-free PPAs, Ampacet PFAS-free aids). Kafrit Group also offers temperature-stable PPAs rated up to 310°C for high-temp polymers like PETG without using fluorochemicals (Kafrit PFAS-free aids).


Regulations Are Heating Up — What This Means For Your Family’s Health

Policy Crackdowns on Forever Chemicals

Governments worldwide are tightening the reins on PFAS:

  • The European Chemicals Agency plans to ban over 10,000 PFAS by 2026—including those commonly found in mold release agents.

  • The U.S. EPA will prohibit fluorinated HDPE containers starting in 2025, affecting filament packaging and raw material storage (EPA regulatory updates).

  • California’s AB 1200 law restricts PFAS use in food-grade printed items, pushing manufacturers toward certified PFAS free filament sources.

Smart Tips to Minimize Exposure at Home

Here’s how I keep my 3D printing setup as safe as possible:

  1. Pick your filament carefully: Stick with PLA, PHA, or PETG rather than composites needing PFAS-laden release agents.

  2. Ventilate like a pro: Use HEPA plus activated charcoal filters that capture ≥99.97% of 0.3μm particles during printing (UW 3D printer safety).

  3. Choose safer post-processing: Try mechanical polishing or closed-loop vapor smoothing systems like Dyemansion’s VaporFuse to avoid exposure to forever chemicals.

  4. Store smart: Transfer filaments from fluorinated plastic packaging into glass or polypropylene containers to stop any leaching shenanigans.


Wrapping It Up: How To Print Safe With PFAS-Free Filament and Protect Your Family

Bottom line? The filaments you use for 3D printing are generally free of those nasty forever chemicals—but beware of sneaky exposures through post-processing solvents, packaging, or specialty composites. Thankfully, smart options like filament without microplastics (think PHA) and engineered alternatives like Tullomer™ give us solid choices to print both strong and safe.

Pair these with good ventilation, toxin-free finishing methods, and careful storage—and you’ve got a winning recipe for healthier prints that keep both your family and our environment happy.

For more peace of mind when shopping, check out the PFAS Free Life database of 3D printing filaments for verified safe picks.

Because honestly—just like we wouldn’t pack forever chemicals in our kids’ lunchboxes, we definitely don’t want them sneaking into our 3D prints!


More from our research . . .

PFAS Free Filament: Avoid Forever Chemicals in 3D Printing

The Real Deal on PFAS in 3D Printing Filaments: What Every Health-Conscious Mom Should Know

Read More →
Switch to PFAS Free Non-Plastic Deodorant Today

Why Every Health-Conscious Parent Should Switch to PFAS Free Deodorant

Read More →
PFAS vs PTFE: Key Differences in Chemicals and Impact

PFAS vs PTFE: What Every Mom Should Know About These Chemicals

Read More →
PFAS in Sparkling Water: Risks and Safe Choices

Presence of PFAS in Sparkling Water: A Comprehensive Analysis

Read More →
PFAS Free HexClad Cookware Without Forever Chemicals

Does HexClad Have PFAS? My Take on PFAS Free HexClad Cookware

Read More →